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METAL-ORGANIC COMPLEX [1 record]

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Record 1 2004-04-26

English

Subject field(s)
  • Chemical Elements and Compounds
OBS

Metallo-organic: of, relating to, or being a compound in which the metal is attached directly to carbon.

CONT

Transient organometallic complexes of CO2. The use of time-resolved FTIR spectroscopy has allowed the observation of new organometallic-CO2 complexes. Photolysis of Rh(Pme3)2(CO)Cl in supercritical CO2 yields a transient neutral cyclometalloanhydride, Rh[C(O)OC(O])(PMe3)2Cl. This metalloanhydride cleanly decomposes back to the starting material. The reactions of this new species along with other transient metal-CO2 complexes will be presented.

French

Domaine(s)
  • Éléments et composés chimiques
OBS

organométallique : Composé organique renfermant au moins une liaison carbone-métal.

Spanish

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