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MIGRATION NIH [1 record]

Record 1 2010-06-22

English

Subject field(s)
  • Chemistry
DEF

The intramolecular hydrogen migration accompanying the molecular rearrangement of arene oxides to cyclohexadienones, thought to be the central step in the enzymic hydroxylation of aromatic rings.

OBS

This phenomenon was extensively studied at the National Institutes of Health and was therefore named "NIH-shift."

French

Domaine(s)
  • Chimie
DEF

Migration intramoléculaire d'un atome d'hydrogène au cours du réarrangement moléculaire des oxydes d'arène en cyclohexadiénones.

OBS

On considère que c'est l'étape clé de l'hydroxylation enzymatique des cycles aromatiques [...]

OBS

NIH pour National Institute of Health.

Spanish

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