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ENOLIZATION [2 records]
Record 1 - internal organization data 2011-08-23
Record 1, English
Record 1, Subject field(s)
- Chemistry
- Biotechnology
Record 1, Main entry term, English
- racemization
1, record 1, English, racemization
correct
Record 1, Abbreviations, English
Record 1, Synonyms, English
Record 1, Textual support, English
Record number: 1, Textual support number: 1 DEF
Conversion, by heat or by chemical reaction(e. g., enolization), of an optically active compound into an optically inactive form, in which half of the optically active substance becomes its mirror-image(enantiomer). 2, record 1, English, - racemization
Record 1, French
Record 1, Domaine(s)
- Chimie
- Biotechnologie
Record 1, Main entry term, French
- racémisation
1, record 1, French, rac%C3%A9misation
correct, feminine noun
Record 1, Abbreviations, French
Record 1, Synonyms, French
Record 1, Textual support, French
Record number: 1, Textual support number: 1 DEF
Réaction chimique transformant un énantiomère en mélange racémique correspondant. 2, record 1, French, - rac%C3%A9misation
Record number: 1, Textual support number: 2 DEF
Transformation spontanée ou provoquée d'un composé optiquement actif en racémique. 3, record 1, French, - rac%C3%A9misation
Record 1, Spanish
Record 1, Campo(s) temático(s)
- Química
- Biotecnología
Record 1, Main entry term, Spanish
- racemización
1, record 1, Spanish, racemizaci%C3%B3n
correct, feminine noun
Record 1, Abbreviations, Spanish
Record 1, Synonyms, Spanish
Record 1, Textual support, Spanish
Record 2 - internal organization data 2004-06-08
Record 2, English
Record 2, Subject field(s)
- Chemistry
Record 2, Main entry term, English
- enolization
1, record 2, English, enolization
correct
Record 2, Abbreviations, English
Record 2, Synonyms, English
Record 2, Textual support, English
Record number: 2, Textual support number: 1 CONT
"Merging Enolization and Bond Construction in the Catalyzed Asymmetric Amination of N-Acyloxazolidinones" [paper written by :] D. A. Evans and S. G. Nelson J. Am. Chem. Soc. 6452 119 1997. 2, record 2, English, - enolization
Record 2, French
Record 2, Domaine(s)
- Chimie
Record 2, Main entry term, French
- énolisation
1, record 2, French, %C3%A9nolisation
correct, feminine noun
Record 2, Abbreviations, French
Record 2, Synonyms, French
Record 2, Textual support, French
Record number: 2, Textual support number: 1 CONT
Nitriles : L'addition du magnésien au nitrile conduit à la formation d'un sel d'immonium. Ce sel d'imine bien qu'insaturé ne réagit pas avec le magnésien car cela impliquerait deux charges négatives sur le même atome d'azote. L'hydrolyse du sel d'immonium le transforme en iminoalcool. En milieu acide ce dernier fournit la cétone plus stable. Cette réaction qui constitue une très bonne méthode de synthèse des cétones possède une limitation dans le cas où l'atome d'hydrogène situé sur l'atome de carbone en a de la fonction nitrile est trop acide. Il y a alors énolisation. 2, record 2, French, - %C3%A9nolisation
Record 2, Spanish
Record 2, Campo(s) temático(s)
- Química
Record 2, Main entry term, Spanish
- enolización
1, record 2, Spanish, enolizaci%C3%B3n
correct, feminine noun
Record 2, Abbreviations, Spanish
Record 2, Synonyms, Spanish
Record 2, Textual support, Spanish
Record number: 2, Textual support number: 1 DEF
Proceso por el que un compuesto carbonílico se convierte en su tautómero enólico. 1, record 2, Spanish, - enolizaci%C3%B3n
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