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FORMATION AZOMETHINE SOUS CATALYSE BASIQUE [1 record]

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Record 1 2000-05-01

English

Subject field(s)
  • Chemical Engineering
CONT

A kinetic study of the mechanism of oxidation of Ala-Gly by aqueous chlorine has been carried out ... The initial chlorination step shows a small isotope effect. In alkaline medium, two consecutive processes take place: first, the general base-catalyzed formation of an azomethine (beta ca. 0.27), which has an inverse deuterium solvent isotope effect ...

French

Domaine(s)
  • Génie chimique
CONT

On a effectué une étude cinétique du mécanisme d'oxydation des peptides Ala-Gly et Pro-Gly par le chlore en milieu aqueux [...] L'étape de chloration initiale ne présente qu'un faible effet isotopique. En milieu alcalin, il se produit deux processus consécutifs : le premier, la formation d'un azométhine sous catalyse basique générale (beta d'environ 0,27) qui présente un effet isotopique inverse pour le deutérium du solvant [...]

Spanish

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