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SUBSTITUE ORTHO [1 record]
Record 1 - internal organization data 2007-07-18
Record 1, English
Record 1, Subject field(s)
- Chemical Elements and Compounds
Record 1, Main entry term, English
- ortho-substituted
1, record 1, English, ortho%2Dsubstituted
correct, see observation, adjective phrase
Record 1, Abbreviations, English
Record 1, Synonyms, English
Record 1, Textual support, English
Record number: 1, Textual support number: 1 CONT
Using n.m.r. methods developed in earlier papers, the conformations of two series, one doubly ortho-substituted and one triply ortho-substituted, of six identically substituted bridged diphenyls were compared. The ethers, sulfides, and methanes have been shown to adopt the same conformation in which the di-ortho-substituted ring is perpendicular to the central bridge plane while the other ring lies in that plane and an ortho hydrogen takes up the "inside" or "proximal" position. 2, record 1, English, - ortho%2Dsubstituted
Record number: 1, Textual support number: 1 OBS
ortho-: Must be italicized. 3, record 1, English, - ortho%2Dsubstituted
Record 1, Key term(s)
- ortho substituted
Record 1, French
Record 1, Domaine(s)
- Éléments et composés chimiques
Record 1, Main entry term, French
- substitué en ortho
1, record 1, French, substitu%C3%A9%20en%20ortho
correct, see observation, adjective phrase
Record 1, Abbreviations, French
Record 1, Synonyms, French
- ortho substitué 2, record 1, French, ortho%20substitu%C3%A9
correct, see observation, adjective phrase
Record 1, Textual support, French
Record number: 1, Textual support number: 1 CONT
En utilisant les méthodes r.m.n. décrites dans les articles précédents on a comparé les conformations de deux séries de six diphényles pontés portant des substituants identiques, l'une doublement substituée en ortho, l'autre triplement substituée en ortho. On a montré que les éthers, les sulfures et les méthanes adoptent une même conformation où le cycle di-ortho substitué est perpendiculaire au plan du pont central, plan qui contient l'autre cycle, un hydrogène ortho occupant la position «intérieure» ou «la plus rapprochée». 3, record 1, French, - substitu%C3%A9%20en%20ortho
Record number: 1, Textual support number: 1 OBS
ortho- : Doit s'écrire en italique. 4, record 1, French, - substitu%C3%A9%20en%20ortho
Record 1, Spanish
Record 1, Textual support, Spanish
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